專家信息：
王勇，男，1979年出生于湖南汨羅，博士生導師�，F任浙江大學求是特聘教授，博士生導師，催化研究所所長。國家重點研發計劃項目首席科學家，中組部“萬人計劃”青年拔尖人才、國家優秀青年基金及杰出青年基金獲得者。2002年本科畢業于湘潭大學化工學院，2007年博士畢業于浙江大學化工系，2007年～2009年在浙江大學化學系從事博士后研究工作，2009年～2011年在德國馬普膠體與界面化學研究所從事博士后研究工作，2011年進入浙江大學工作至今。榮獲第九屆中國催化青年獎、侯德榜化工科技-創新獎等榮譽。作為項目負責人先后承擔多項國家及省部級項目，如國家自然科學基金優秀青年基金、面上項目以及浙江省杰出青年基金和重點基金等項目。王勇課題組致力于工業催化劑的研發，特別是基于多孔炭及金屬氧化物的負載型工業催化劑的開發及相關反應機理的研究，所研發的多個催化劑在工業上得到應用, 產生了顯著的經濟和社會效益。在Chem., J. Am. Chem. Soc., Nat. Commun., Angew. Chem. Int. Ed.等期刊上發表SCI論文170余篇，被引用2.3萬余次，H-index 66。獲授權國家發明專利40余件。入選“高被引學者”名單，研究成果榮獲中國專利金獎、中國石油與化學工業聯合會“發明特等獎”、浙江省科學技術獎-技術發明一等獎以及浙江省自然科學一等獎等榮譽。
教育及工作經歷：
2002年本科畢業于湘潭大學。
2007年博士畢業于浙江大學化工系，獲工學博士學位，博士論文被評為浙江省優秀博士論文以及全國百篇優秀博士論文提名獎論文。
2007年～2009年在浙江大學化學系從事博士后研究工作，合作導師李浩然教授，并榮獲“浙江省優秀博士后”稱號。
2009年4月～2011年3月在德國馬普膠體與界面化學研究所從事博士后研究工作，合作導師Markus Antonietti教授。
2011年4月起回國擔任浙江大學化學系特聘研究員。
學術兼職：
1、擔任國際期刊Scientific Reports的編委。
主講課程
資料更新中……
培養研究生情況：
在讀博士生12名，在讀碩士生7名，畢業博士生2名。
招生信息：
1. 歡迎本科生同學來課題組開展科研實驗或做畢業設計；
2. 課題組每年招收博士研究生3名，碩士研究生2名；
3.課題組招收博士后多名，歡迎具有多相催化、電催化、材料、有機及理論計算等背景的博士來課題組從事博士后研究工作（待遇面議）。
研究方向：
Professor Wang’s advanced materials and catalysis research group has been focusing its efforts on the basic science and applied research for the design and development of heterogeneous catalysis, energy storage, and energy conversion carbon based materials. They strive to pursue green energy technologies and the beautiful fundamental science that make these technologies a reality.
(i) The use of biomass as renewable raw materials conforms to the conception of Green Chemistry. Besides the sustainability of the bio-carbon, the conversion of biomass to functional materials provided an effective route to add to the value of fabricated products. We focus on exploring the novel and green methods to synthesize carbon materials with controllable morphology, porous structure, and functional surface on the basis of biomass and derivatives.
Selected Publications:
(1) Chen, C. H.; Mao, S. J.; Tan, C. L.*; Wang, Z.; Ge, Y. Y.; Ma, Q. L.; Zhang, X.; Qi, G. D.; Xu, J.; Fan, Z. X.; Wang, Y*. General synthesis of ordered mesoporous carbonaceous hybrid nanostructures with molecularly dispersed polyoxometallates, Angew. Chem. Int. Ed., 2021, 60, 15556-15562.
(2) Liu, J. R.; Xie, L.; Deng, J.; Gong, Y. T.; Tang, G. P.; Bai, H. Z.*, Wang, Y.* Annular mesoporous carbonaceous nanospheres from biomass-derived building units with enhanced biological interactions, Chem. Mater., 2019, 31, 7186-7191.
(3) Chen, C. H.; Wang, H. Y.; Han, C. L.; Deng, J.; Wang, J.; Li, M. M.; Tang, M. H. Jin, H. Y.; Wang, Y.*, Asymmetric flask-like hollow carbonaceous nanoparticles fabricated by the synergistic interaction between soft template and biomass. J. Am. Chem. Soc., 2017, 139, 2657-2663.
(4) Deng, J.; Xiong, T. Y.; Xu, F.; Li, M. M.; Han, C. L.; Gong, Y. T.; Wang, H. Y.; Wang, Y.* Inspired by bread leavening: One-pot synthesis of hierarchically porous carbon for supercapacitors. Green Chem., 2015, 7, 4053-4060.
(5) Zhang, P. F.; Yuan, J. Y.*; Tim-Patrick,F.; Antonietti, M.; Li, H. R.; Wang, Y.* Improving hydrothermal carbonization by poly(ionic liquid)s. Angew. Chem. Int. Ed., 2013, 52, 6028-6032.
(ii) We are also committed to developed N-doped carbon based composites supported metal and non-noble metal as low-cost and highly efficient catalysts. Moreover, the mechanisms of reactions have been investigated both experimentally and with density functional theory (DFT) modeling. To be sure, the synthesis strategy provides a versatile platform to introduce various metal species on nitrogen-doped carbon with targeted and improved properties for diverse catalytic reactions.
Selected Publications:
(1) Ning, H. H.; Chen, Y. Z.; Wang, Z. Z.; Mao, S. J.*; Chen, Z. R.; Gong, Y. T.; Wang, Y.* Selective upgrading of biomass-derived benzylic ketones by (formic acid)-Pd/HPC-NH2 system with high efficiency under ambient conditions, Chem, 2021, 7,3069-3084.
(2) Wang, Z. Z.; Liang, S. P.; Meng, X. Y.; Mao, S. J.*; Lian, X.; Wang, Y.* Ultrasmall PdAu alloy nanoparticles anchored on amine-functionalized hierarchically porous carbon as additive-free catalysts for highly efficient dehydrogenation of formic acid. Appl. Catal. B Environ., 2021, 291, 120140.
(3) Wang, C. P.; Mao, S. J.*; Wang, Z.; Chen, Y. Z.; Yuan, W. T.; Ou Y.; Zhang, H.; Gong, Y. T.; Wang, Y.; Mei, B. B.; Jiang, Z.; Wang, Y.* Insight into Single-atom Induced Unconventional Size-dependence over CeO2-supported Pt Catalysts, Chem., 2020, 6, 752-765.
(4) Mao, S. J.; Wang, C. P.; Wang, Y.* The chemical nature of N doping on N doped carbon supported noble metal catalysts. J. Catal., 2019, 375, 456-465.
(5) Xu, X.; Li, Y.; Gong, Y. T.; Zhang, P. F.; Li, H. R.; Wang, Y.* Synthesis of palladium nanoparticles supported on mesoporous N-doped carbon and their catalytic ability for biofuel upgrade. J. Am. Chem. Soc., 2012, 134, 16987-16990.
(iii) As growing demand for energy in the future, energy conversion and storage are of great interest in our research group. Due to green chemistry, electric energy gained hot research concentration and will experience fast growth. Thus, electrical catalysts for energy conversion are our focused highlights.
Selected Publications:
(1) Chen, J. D.; Qin, M. K.; Ma, S. X.; Fan, R. X.; Zheng, X. Z.; Mao, S. J.; Chen, C. H.; Wang, Y*. Rational construction of Pt/PtTex interface with optimal intermediate adsorption energy for efficient hydrogen evolution reaction, Appl. Catal. B Environ., 2021, 299, 120640.
(2) Wang, J.; Wei, Z. Z.; Mao, S. J.; Li, H. R.; Wang, Y.*, Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction, Energ. Environ. Sci., 2018, 11, 800-806.
(3 Wang, J.; Xu, F.; Jin, H. Y.; Chen, Y. Q.; Wang, Y.*, Non-noble metal-based carbon composites in hydrogen evolution reaction: fundamentals to applications, Adv. Mater., 2017, 29, 1605838.
(4) Wang, S. P.; Wang, J.; Zhu, M. L.; Bao, X. B.; Xiao, B. Y.; Su, D. F.; Li, H. R.; Wang, Y.* Molybdenum carbide-modified nitrogen-doped carbon vesicle encap-sulating nickel nanoparticles: A highly efficient, low-cost catalyst for hydrogen evolution reaction. J. Am. Chem. Soc., 2015, 137, 15753-15759.
(5) Jin, H. Y.; Wang, J.; Su, D. F.; Wei, Z. Z.; Pang, Z. F.; Wang, Y.* In-situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bi-functional electrocatalysts for hydrogen and oxygen evolution. J. Am. Chem. Soc., 2015, 137, 2688.
承擔科研項目情況：
作為項目負責人承擔多項國家自然科學基金、浙江省杰出青年基金及教育部博士點基金等。
1. 國家自然科學基金杰出青年基金，22325204，負載型納米金屬催化劑及應用 ，2024/01-2027/12，在研，負責人：王勇。
2. 浙江省“尖兵”研發攻關計劃項目，2023C01108, 高端香料二氫茉莉酮酸甲酯的精準合成及產業化, 2022/09-2025/09，在研，負責人：王勇。
3. 科技部國家重點研發計劃項目，2021YFB3801600，重要反應過程貴金屬等效減量的關鍵技術開發及應用示范，2021/12-2024/11, 在研，首席科學家：王勇。
4. 浙江省“領雁”研發攻關計劃項目，2022C01151，高效電催化二氧化碳還原催化劑的開發及示范化應用，2021/09-2024/08，在研，負責人：楊瑞。
5. 浙江省“領雁”研發攻關計劃項目，2022C01218，高性能催化材料開發及應用-高效多相羰基化催化劑的開發以及應用，2021/09-2024/06，在研，負責人：毛善俊。
6. 企業橫向經費，202133000400，強力霉素氫化工藝改進項目，2021/06-2022/06, 結題，負責人：王勇。
7. 企業橫向經費，環己醇脫氫制備環己酮高效催化劑開發，2021/04-2022/09, 結題，負責人：王勇。
8. 企業橫向經費，K橫20201745，高性能納米金屬催化劑研制及應用，2020/01-2025/12，在研，負責人：王勇。
9. 浙江省重點研發計劃項目，2020C01133，高性能加氫催化劑的精準合成及產業化應用研究，2019/09-2022/08，結題，負責人：毛善俊。
10. 國家自然科學基金青年項目，21908189，鹵代芳胺合成中的關鍵脫鹵因素研究以及高效催化劑設計，2020/01-2022/12，結題，負責人：毛善俊。
11. 國家自然科學基金面上項目，21872121，炔醇加氫機理研究及高效催化劑的開發，2019/01-2022/12，結題，負責人：王勇。
12. 國家自然科學基金青年項目，21802120，三元金屬間化合物負載Ru催化劑的設計合成及其合成氨催化性能研究，2019/01-2021/12，結題，負責人：鞏玉同。
13. 浙江省自然科學基金重點項目，LZ18B060002，維生素E產業鏈中關鍵中間體高性能加氫催化劑的開發，2018/01-2021/12，提前結題，負責人：王勇。
14. 國家自然科學基金優秀青年基金項目，21622308，炭材料與多相催化，2017/01-2019/12，結題，負責人：王勇。
15. 國家重點研發專項子課題，2016YFA0202900，微納結構有機分子催化材料，2016/07-2021/06，結題，負責人：王勇。
16. 中組部萬人計劃“青年拔尖人才”項目，2016/01-2018/12，結題，負責人：王勇。
17. 國家自然科學基金重大研究計劃項目培育項目，91534114，芳環加氫炭負載型多相催化劑的多尺度設計及研制，2016/01-2018/12，結題，負責人：王勇。
18. 國家自然科學基金面上項目，21376208，用于取代硝基化合物選擇性加氫反應的納米催化劑研制、2014/01-2017/12，結題，負責人：王勇。
19. 浙江省自然科學基金杰出青年基金，LR13B030001，基于碳氮材料納米催化劑的制備及應用研究、LR13B03001，2013/01-2016/12，結題，負責人：王勇。
20. 浙江大學-馬普膠體與界面化學研究所伙伴計劃，碳基納米催化劑及其在生物質轉化中的應用，2011/11-2016/11，結題，負責人：王勇。
21. 企業橫向經費，H20150385，苯酚氣相加氫制備環己酮催化劑開發，2015/01-2018/12，在研，負責人：王勇。
22. 教育部博士點基金-博導類，J20130060，多孔氮化碳負載的納米金屬催化劑及其在喹啉選擇性加氫反應中的應用，2013/01-2015/12，結題，負責人：王勇。
23. 國家自然科學基金石油化工聯合基金培育項目，U1162124，基于三維介孔氮化碳的多功能催化劑的設計與研制，2012/01-2014/12，結題，負責人：王勇。
24. 企業橫向經費，H20112656，苯酚加氫制備環己酮技術，2011/09-2015/09，結題，負責人：王勇。
25 .國家自然科學基金-青年科學基金，20806065，結合譜學和理論計算研究質子型離子液體的微觀結構，2009/01-2011/12，結題，負責人：王勇。
科研成果：
1.迄今已在Nat. Commun.,J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Mater.; J. Catal.等國際知名刊物上發表科研論文100余篇，H因子26。
發明專利：
1. 王勇，鄭曉忠，楊瑞，陸冰，羅乾，劉彥玲，氧化釩負載型高分散且結構畸變的納米簇催化劑及其制備方法和應用，ZL 202210019482.X
2. 王勇，王珍珍，毛善俊，梁世潘，一種高比表面積金屬氧化物及其制備方法和應用，ZL 202110894884.X
3. 王勇，陸冰，毛善俊，王哲， 一種用于碳碳偶聯反應的酸堿雙位點催化劑及其應用， ZL 202111213624.8.
4. 王勇，陸冰，陳春紅，毛善俊,單分子雜多酸鑲嵌的蜂窩狀炭材料負載的納米金屬催化劑及其制備方法和應用,ZL 202010107709.7
5. 王勇，陳宇卓，羅乾，毛善俊,一種負載型催化劑及其制備方法和應用,ZL201911084810.9
6. 王勇，陳春紅，陸冰，毛善俊,一種多孔炭負載型單分子雜多酸催化劑及其制備方法和應用,ZL202010108012.1
7. 李浩然，王勇，胡柏剡，馬嘯，仇丹，羅乾，王哲，毛善俊，于麗麗，李其川，一種選擇性加氫催化劑及其制備方法和應用，ZL 202010102438.6
8. 王勇；劉錦蓉；謝磊；鄧江；鞏玉同,一種類齒輪狀介孔炭納米球材料、制備方法及應用, ZL201910039858.1
9. 王勇；鞏玉同；王哲；毛善��；陳佳東；李浩然,一種高分散負載型催化劑及其制備方法和應用,ZL201910451496.7
10. 王勇，方忠鋒，一種醋酸乙酯加氫制乙醇的催化劑及其制備方法和應用，ZL 201810175970.3
11. 王勇，王哲，毛善俊，鞏玉同，寧紅輝，陳佳東，一種選擇性加氫催化劑在加氫反應中作為催化劑的應用，ZL201910452579.8
12. 王勇，陳益慶，曹月領，王哲，一種高分散納米金屬氧化物復合的炭材料及其制備方法和應用，ZL201810765050.7
13. 王勇，孔祥千，毛善俊，王春鵬，陳宇卓，一種高分散納米催化劑的制備方法，ZL201711228648.4.
14. 王勇；陳佳東，單分散的金屬-單寧酸包覆活化碳布的催化劑及其制備方法和應用, ZL201910211520.X
15. 王勇，毛善俊，王哲，一種氮摻雜多級孔炭負載的納米Pd催化劑的制備方法及其產品和應用，ZL201911028624.3
16. 王勇，王哲，毛善俊，陳益慶，趙博文，炔醇選擇性加氫催化劑及其制備方法和應用，ZL201811043834.5
17. 王勇；鄧江；王海燕，一種柔性鋰離子電容器用負極材料及其制備方法和應用，ZL201711237123.7
18. 王勇，陳佳熠，王哲，王海燕，一種高效分散鉬基催化劑的制備方法及其應用，ZL201910125706.3
19. 王勇，馬嘯，于麗麗，王哲，毛善俊，李建清，陳鋼，李浩然，陳志榮，PdIn合金催化劑及其制備方法、應用，ZL201811010568.6
20. 王勇，呂國鋒，于麗麗，王哲，毛善俊，唐靜思，李浩然，陳志榮，復合催化劑及其制備方法、應用，ZL201811010567.1
21. 王勇，王海燕，一種二氧化錳/超微孔柔性碳布的制備方法、產品及應用，ZL201611191041.9.
22. 王勇, 謝磊, 貝殼狀超結構炭材料的制備方法及產品, ZL 2017106646209.
23. 王勇，李名明，鄧江，氮摻雜多級孔炭及其制備方法和應用，ZL 201610492985.3.
24. 王勇，于麗麗，李建清，陳鋼，李名明，沈凌峰，張玉霞，陳志榮，李浩然，王柳楓，陶娟娟，一種用于炔醇選擇性加氫的催化劑及其制備方法和應用，ZL201610707572.2
25. 王勇，王靜，魏中哲，王海燕，3D多孔電極的制備方法及其在電化學析氫反應中的應用，ZL 201610640590.3
26. 王勇，陳春紅，韓傳龍，鄧江，中空炭材料的制備方法及其產品，ZL 2016 1 0388548.7
27. 王勇，鮑曉冰，鞏玉同，一種Fe-N-C氧還原催化劑及其合成方法和應用，ZL 201610288312.6
28. 王勇，鄧江，李建清，湯明慧，李名明，一種利用回收廢炭制備含氮多孔炭的方法及其產品和應用，ZL 201610487519.6
29. 王勇，王靜，魏中哲，李浩然，王世萍，韓傳龍，一種基于碳管與過渡金屬復合的催化劑制備烯烴類化合物的方法，ZL 2015 1 0026459.3
30. 王勇，王海燕，一種制備超微孔碳布的方法及其產品和應用，ZL 201610107519.9
31. 王柳楓 徐志超 李建清 王勇 李浩然 陳志榮，一種生物素中間體加氫鈀炭催化劑的再活化方法，ZL201611228094.3
32. 王勇，王海燕，一種錳的氧化物/多孔炭納米纖維復合材料的制備方法及其產品和應用，ZL 2014 1 0727218.7
33. 王勇，鄧江，熊天一，蘇疊峰， 徐凡，一種多級孔碳材料的制備方法及產品，ZL 2014 1 0796050.5
34. 王勇，王世萍，韓傳龍，王靜，朱明蕾，表面功能化的有序介孔摻氮炭材料的制備方法，ZL 2014 1 0309930.5
35. 王勇，魏中哲，王靜，一種用于芳硝基化合物選擇性加氫反應的多相催化劑及其應用，ZL201410389748.5
36. 王勇，鄧江，熊天一，鞏玉同，徐凡，一種納米級層狀二氧化硅/石墨烯復合材料的制備方法及其產品，ZL201410797490.2
37. 王勇，王世萍，韓傳龍，王世國，王靜，肖冰洋，一種摻氮碳納米管的制備方法及其產品，ZL201410401402.2
38. 王勇，王靜，鞏玉同，王世萍，韓傳龍，一種大管徑、超長納米碳管的制備方法，ZL201410338644.1
39. 王勇，張鵬飛，一種基于離子熱過程的多孔炭材料制備方法，ZL201310328455.1
40. 王勇，鞏玉同，一種多孔碳的制備方法及其產品，ZL201410038705.2
41. 王勇，徐旋，芳香化合物催化加氫制備環己基化合物的方法，ZL201310012978.5
42. 王勇，徐旋，鞏玉同，李浩然，一種新型介孔碳擔載的金屬催化劑及其制備方法，ZL201110387825.X
43. 王勇，鞏玉同，李浩然，一種苯甲醛類化合物的制備方法及其用新型介孔碳擔載的雙金屬催化劑，ZL201110387822.6
44. 王勇，張鵬飛，一種小尺寸實心碳球的制備方法及制備得到的碳球，ZL201210562902.5
45. 王勇，張鵬飛，李浩然，一種硫化物的選擇性氧化方法，ZL201110390268.7
46. 王勇，徐旋，李翼，李浩然，一種芳香族硝基化合物選擇性加氫還原方法，ZL201110389173.3
在Nature Commun., J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Commun.; Chem. Mater.; J. Catal. 等國際知名刊物上累積發表論文70余篇，被引2300多次，h-index 26。
發表英文論文
2024年
1. Jinqi Xiong, Shanjun Mao*, Qian Luo, Honghui Ning, Bing Lu, Yanling Liu and Yong Wang*, Mediating trade-off between activity and selectivity in alkynes semi-hydrogenation via a hydrophilic polar layer, Nat. Commun., 2024, 15, 1228.
2. Zhe Wang, Chunpeng Wang, Bing Lu, Zhirong Chen, Yong Wang*, Shanjun Mao*, Electronic perturbation-promoted interfacial pathway for facile C-H dissociation, Chin. J. Catal., 2024, 56, 130-138.
2023年
1. Honghui Ning, Xiaozhong Zheng, Jinqi Xiong, Bing Lu, Yong Wang, Kaichao Zhang, and Shanjun Mao*, Rebalancing Hydrogenation and Dehydration Performances for Efficient Hydrodeoxygenation of Biomass Derivatives to Match Reaction Temperature-Induced Rate-Determining Step Switch, Ind. Eng. Chem. Res., 2023, 62, 44, 18403–18415
2. Xiaotong Li, Minkai Qin, Xiuju Wu, Xiangzhou Lv, Jianghao Wang, Yong Wang*, Hao Bin Wu*, Enhanced CO Affinity on Cu Facilitates CO2 Electroreduction toward Multi-Carbon Products, Small, 2023, 2302530.
3. Xiaoyun Shi†, Xiaozhong Zheng†, Hao Wang, Hao Zhang, Minkai Qin, Binbin Lin, Menghui Qi, Shanjun Mao, Honghui Ning, Rui Yang, Lingling Xi*, Yong Wang*, Hierarchical Crystalline/Amorphous Heterostructure MoNi/NiMoOx for Electrochemical Hydrogen Evolution with Industry-Level Activity and Stability，Adv. Funct. Mater., 2023, 2307109.
4. 毛善俊、王哲、王勇*，“基團辨識加氫”：從概念到應用，《化工進展》, 2023, 42, 3917-3922.
5. Xiaozhong Zheng, Xiaoyun Shi, Honghui Ning, Rui Yang, Bing Lu, Qian Luo, Shanjun Mao, Lingling Xi, Yong Wang*, Tailoring a local acid-like microenvironment for efficient neutral hydrogen evolution, Nat. Commun., 2023, 14, 4209.
6. Minkai Qina, Menghui Qia, Ruxue Fan, Jiadong Chena, Xiaoyun Shi, Binbin Lin, Lingling Xi, Yong Wang*, K Intercalation-assisted Co-doped MoS2 Nanoflowers for Efficient Hydrogen Evolution Reaction, Precis. Chem., 2023, doi.org/10.1021/prechem.3c00033.
7. Liwei Zhang, Shanjun Mao,* Yali Liu, Bing Lu, Yongtao Wang, Haoran Li* and Yong Wang* Tandem Catalytic Efficient Olefin Epoxidation with Integrated Production of Nicotinamide Derivatives, Chem Catal., 2023, 3, 100691.
8. Yuzhuo Chen, Hao Wang, Bing Lu, Ni Yi, Liang Cao, Yong Wang, Shanjun Mao*, Fine-structure sensitive deep learning framework for prediction of catalytic properties with high precision,Chin. J. Catal., 2023, 50, 284-296.
9. Lihua Wang, Shuangxiu Ma, Chunhong Chen, Bing Lu, Zhe Wang, Yong Wang, and Shanjun Mao*, Pentacoordinated Al3+ stabilized polyoxometalates for the efficient catalytic valorization of biomass-derived feedstocks, Catal. Sci. Technol., 2023, 13, 3558-3567.
10. Bing Lu, Shuangxiu Ma, Shipan Liang, Zhe Wang, Yali Liu, Shanjun Mao, Heng Ban, Lihua Wang, Yong Wang,* Efficient conversion of ethanol to 1-butanol over adjacent acid-base dual sites via enhanced C-H activation, ACS Catal., 2023, 13, 4866-4872.
11. Mao, Shanjun; Wang, Zhe; Luo, Qian; Lu, Bing; Wang, Yong*, Geometric and electronic effects in hydrogenation reactions, ACS Catal., 2023, 13, 974-1019.
12. Yutong Gong, Lei Xie, Chunhong Chen, Jinrong Liu, Markus Antonietti*, Yong Wang*, Bottom-up Hydrothermal Carbonization for the Precise Engineering of Carbon Materials, Prog. Mater. Sci., 2023, 132, 101048.
2022年
1. Jiadong Chen, Chunhong Chen, Minkai Qin, Ben Li, Binbin Lin, Qing Mao, Hongbin Yang, Bin Liu*, Yong Wang*, Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting, Nat. Commun., 2022, 13, 5382.
2. Binbin Lin†, Jiadong Chen†, Rui Yang, Shanjun Mao, Minkai Qin, Yong Wang*, Multi-hierarchical cobalt-based electrocatalyst towards high rate H2 production, Appl. Catal. B Environ., 2022, 316, 121666.
3. Zhe Wang#, Chunpeng Wang#, Shanjun Mao*, Bing Lu, Yuzhuo Chen, Xie Zhang, Zhirong Chen, Yong Wang*, Decoupling the Electronic and Geometric Effects of Pt Catalysts in Selective Hydrogenation Reaction, Nat. Commun., 2022, 13, 3561.
4. Minkai Qin, Jiadong Chen, Xiaozhong Zheng, Menghui Qi, Rui Yang, Shanjun Mao, Yong Wang*, Operando deciphering the activity origins for potential-induced reconstructed oxygen-evolving catalysts, Appl. Catal. B Environ., 2022, 316, 121602.
5. Zhe Wang, Qian Luo, Shanjun Mao, Chunpeng Wang, Jinqi Xiong, Zhirong Chen, Yong Wang*, Fundamental aspects of alkyne semi-hydrogenation over heterogeneous catalysts, Nano Res., 2022, 15, 10044–10062.
6. Ruxue Fan, Haiyan Wang, Xiaozhong Zheng, Jiadong Chen, Yang Ou, Yong Wang, Shanjun Mao*, Fe2 Dimers for Non-Polar Diatomic O2 Electroreduction, ChemSusChem, 2022, 15, e202200532.
7. Xie Zhang, Chunhong Chen*, Chenyang Tang, Yong Wang*, Morphological Control of Biochar with Emerging Functionalities by Thermodynamic and Kinetic Approaches, Acc. Mater. Res., 2022, 3, 525-539.
8. Rui Yang, Xiaozhong Zheng, Minkai Qin, Binbin Lin, Xiaoyun Shi, Yong Wang*, A trifunctional Ni-P/Fe-P collaborated electrocatalyst enables self-powered energy systems, Adv. Sci., 2022, 2201594.
9. Minkai Qin, Ruxue Fan, Jiadong Chen, Haiyan Wang, Xiaozhong Zheng, Shanjun Mao, Renfeng Du, Yong Wang*, Elucidating electrocatalytic mechanism for large-scale cycloalkanol oxidation integrated with hydrogen evolution, Chem. Eng. J., 2022, 442, 136264.
10. Xiaozhong Zheng, Minkai Qin, Shuangxiu Ma, Yuzhuo Chen, Honghui Ning, Rui Yang, Shanjun Mao, and Yong Wang*, Strong Oxide-Support Interaction over IrO2/V2O5 for Efficient pH-Universal Water Splitting, Adv. Sci., 2022, 2104636.
11. Lei Xie, Jinrong Liu, Xiaobing Bao, Jiadong Chen, Xiaozhong Zheng, Yanjun He, Wei Zhang, Jie Zeng, Yong Wang*, Biao Kong*, Interfacial Assembly of Nanowire Arrays toward Carbonaceous Mesoporous Nanorods and Superstructures, Small, 2022, 18, 2104477.
12. Chunpeng Wang#, Zhe Wang#, Shanjun Mao, Zhirong Chen, Yong Wang*, Coordination Environment of Active Sites and Their Effect on Catalytic Performance of Heterogeneous Catalysts, Chin. J. Catal., 2022, 43, 928-955.
2021年
1. Bing Lu, Zhe Wang, Shuangxiu Ma, Shanjun Mao, Zhirong Chen, and Yong Wang*, Spatial Charge Separation Induced New Mechanism of Efficient C-C Coupling by Forming Ion-Pair Intermediates, Chem Catal., 2021, 1, 1449-1465.
2. Chunhong Chen, Yong Wang*, The precise engineering of nanostructured carbon materials, ACS Cent. Sci., 2021, 7, 1470-1472.(First Reactions)
3. Jiadong Chen, Minkai Qin, Shuangxiu Ma, Ruxue Fan, Xiaozhong Zheng, Shanjun Mao, Chunhong Chen and Yong Wang* Rational Construction of Pt/PtTex Interface with Optimal Intermediate Adsorption Energy for Efficient Hydrogen Evolution Reaction, Appl. Catal. B Environ., 2021, 299, 120640.
4. Honghui Ning, Yuzhuo Chen, Zhenzhen Wang, Shanjun Mao,*, Zhirong Chen, Yutong Gong and Yong Wang*, Selective Upgrading of Biomass-derived Benzylic Ketones by (Formic Acid)-Pd/HPC-NH2 System with High Efficiency under Ambient Conditions, Chem, 2021, 7,3069-3084.
5. Qian Luo,†,# Zhe Wang,†,# Yuzhuo Chen,† Shanjun Mao,*,† Kejun Wu,‡ Kaichao Zhang,‡ Qichuan Li,‡ Guofeng Lv,‡ Guodong Huang,‡ Haoran Li,† and Yong Wang*,† Dynamic Modification of Palladium Catalysts with Chain Alkylamines for the Selective Hydrogenation of Alkynes, ACS Appl. Mater. & Inter., 2021, 13, 31775-31784.
6. Chunhong Chen, Shanjun Mao, Chaoliang Tan,* Zhe Wang, Yiyao Ge, Qinglang Ma, Xiao Zhang, Guodong Qi, Jun Xu, Zhanxi Fan, and Yong Wang*, General Synthesis of Ordered Mesoporous Carbonaceous Hybrid Nanostructures with Molecularly Dispersed Polyoxometallates, Angew. Chem. Int. Ed.,2021, 60, 15556-15562.
7. Lei Xie, Shan Zhou, Jinrong Liu, Beilei Qiu, Tianyi Liu, Qirui Liang, Xiaozhong Zheng, Ben Li, Jie Zeng, Miao Yan, Yanjun He, Xin Zhang, Hui Zeng, Ding Ma, Pu Chen, Kang Liang, Lei Jiang, Yong Wang*, Dongyuan Zhao*, and Biao Kong*, Sequential Superassembly of Nanofiber Arrays to Carbonaceous Ordered Mesoporous Nanowires and Their Heterostructure Membranes for Osmotic Energy Conversion,J. Am. Chem. Soc. 2021, 143, 6922-6932.
8. Zhenzhen Wang, Shipan Liang, Xiaoyan Meng, Shanjun Mao*, Xu Lian, and Yong Wang*, Ultrasmall PdAu Alloy Nanoparticles Anchored on Amine-functionalized Hierarchically Porous Carbon as Additive-free Catalysts for Highly Efficient Dehydrogenation of Formic Acid. Appl. Catal. B Environ., 2021, 291, 120140.
2020年
1. Shanjun Mao1, Zhe Wang1, Zhirong Chen2, Kejun Wu3, Kaichao Zhang3, Qichuan Li3, Huihuan Yan3, Guofeng Lü3, Guodong Huang3, and Yong Wang1*, Towards the selectivity distinction of phenol hydrogenation on noble metal catalysts, Nano Mater. Sci., 2023, 5, 91-100.
2. Jiadong Chen,# Chunhong Chen,# Yuzhuo Chen, Haiyan Wang, Shanjun Mao, and Yong Wang*, Improving Alkaline Hydrogen Evolution Reaction Kinetics on Molybdenum Carbide: Introducing Ru dopant. J. Catal., 2020, 392, 313-321.
3. Xiaozhong Zheng, Yuzhuo Chen, Xiaobing Bao, Shanjun Mao, Ruxue Fan, and Yong Wang*, In-Situ Formed Bimetallic Carbide Ni6Mo6C Nanodots and NiMoOx Nanosheet Arrays Hybrids Anchored on Carbon Cloth: Efficient and Flexible Self-supported Catalysts for Hydrogen Evolution, ACS Catal., 2020, 10, 19, 11634-11642.
4. Zhe Wang1, Yuzhuo Chen1, Shanjun Mao1, Kejun Wu2, Kaichao Zhang2, Qichuan Li2 and Yong Wang1*, Chemical insight into the structure and formation of coke on PtSn alloy during propane dehydrogenation, Adv. Sustain. Syst., 2020, 2000092.
5. Xiaobing Bao1, Yutong Gong1, Xiaozhong Zheng, Jiayi Chen, Shanjun Mao, Yong Wang*, Highly performed platinum nanosheets synthesized under in situ reaction conditions for hydrogen generation, J. Ener. Chem., 2020, 51, 272-279.
6. Chunpeng Wang, Shanjun Mao*, Zhe Wang, Yuzhuo Chen, Wentao Yuan, Yang Ou, Hao Zhang, Yutong Gong, Yong Wang, Bingbao Mei, Zheng Jiang, and Yong Wang*,Insight into Single-atom Induced Unconventional Size-dependence over CeO2-supported Pt Catalysts, Chem., 2020, 6, 752-765.
7. Jinrong Liu,‡ Lei Xie,‡ Zhe Wang, Shanjun Mao, Yutong Gong, and Yong Wang*, Biomass-derived ordered mesoporous carbon nano-ellipsoids encapsulated metal nanoparticles inside: ideal nanoreactors for shape-selective catalysis. Chem. Commun., 2020, 56, 229-232.
2019年
1. Haiyan Wang, Yuzhuo Chen, Ruxue Fan, Jiadong Chen, Zhe Wang, Shanjun Mao, Yong Wang*, Selective Electrochemical Reduction of Nitrogen to Ammonia by Adjusting the Three-Phase Interface, Research, 2019, 2019, 1401209.
2. Zhenzhen Wang, Chunpeng Wang, Shanjun Mao, Yutong Gong, Yuzhuo Chen and Yong Wang*, Pd nanoparticles anchored on amino-functionalized hierarchically porous carbon for efficient dehydrogenation of formic acid at ambient condition, J. Mater. Chem. A, 2019,7, 25791-25795.
3. Lei Xie, Zhe Wang, Jinrong Liu, Yutong Gong, Shanjun Mao, Guofeng Lü, Xiao Ma, Lili Yu, Yong Wang, Kinetics-controlled synthesis of hierarchically porous materials with tunable properties from diverse building blocks, Carbon, 2019,155, 611-617.
4. Shanjun Mao, Bowen Zhao, Zhe Wang, Yutong Gong, Guofeng Lü, Xiao Ma, Lili Yu, Yong Wang, Tuning the Catalytic Performance for the Semi-hydrogenation of Alkynols by Selectively Poisoning the Active Sites of Pd Catalysts, Green Chem., 2019, 21, 4143-4151.
5. Jinrong Liu, Lei Xie, Jiang Deng, Yutong Gong, Guping Tang, Hongzhen Bai*, Yong Wang*, Annular mesoporous carbonaceous nanospheres from biomass-derived building units with enhanced biological interactions, Chem. Mater., 2019, 31, 7186-7191.
6. Shanjun Mao; Chunpeng Wang; Yong Wang*, The chemical nature of N doping on N doped carbon supported noble metal catalysts. J. Catal., 2019, 375, 456-465.
7. Wang, Haiyan; Fan, Ruxue; Miao, Jingyu; Deng, Jiang; Wang, Yong*, Oxygen Groups Immobilized in Micropores for Enhancing the Pseudocapacitance, ACS Sus. Chem. & Eng., 2019, 7, 11407-11414.
8. Yong Wang, Preface to special issue on celebrating the 40th anniversary of Institute of Catalysis, Zhejiang University, Chin. J. Catal., 2019, 40, 969-970 (Preface).
9. Xiaobing Bao,a Yutong Gong,*a Yuzhuo Chen,a Hao Zhang,b Zhe Wang,a Shanjun Mao,a Lei Xie,a Zheng Jiang*b and Yong Wang*a, Carbon vacancy defect-activated Pt cluster for hydrogen generation, J. Mater. Chem. A 2019, 7, 15364-15370.
10. Jiayi Chen, Haiyan Wang, Zhe Wang, Shanjun Mao, Jian Yu, Yong Wang, Yong Wang *, Re-dispersion of Mo-based Catalysts and the Rational Design of Super Small-sized Metallic Mo Species, ACS Catal., 2019, 9, 5302-5307.
11. Yuzhuo Chen, Xiangqian Kong, Shanjun Mao, Zhe Wang,Yutong Gong, Yong Wang*, Study on the Role of Alkaline Sodium Additive in Selective Hydrogenation of Phenol, Chin. J. Catal., 2019, 40, 1516-1524.
12. Jiadong Chen, Haiyan Wang*, Yutong Gong and Yong Wang*, Directly Immobilizing Ru-Tannic Acid linkage coordination Complex on Carbon Cloth: An Efficient and Ultrastable Catalyst for Hydrogen Evolution Reaction, J. Mater. Chem. A, 2019,7, 11038-11043 (2019 Journal of Materials Chemistry A HOT Papers)
13. Yuzhuo Chen, Zhe Wang, Shanjun Mao, Yong Wang*，Rational design of hydrogenation catalysts by using nitrogen doped porous carbon，Chin. J. Catal., 2019, 40, 971-979.
14. Chunhong Chen, Lei Xie, and Yong Wang*, Recent advances in the synthesis and applications of anisotropic carbon and silica-based nanoparticles, Nano Research, 2019, 12, 1267-1278 (Invited Review).
2018年
1. Xuefeng Li‡, Zhe Wang‡, Shanjun Mao*, Yiqing Chen, Minghui Tang, Haoran Li, Yong Wang*, Insight into the Role of Additives in Catalytic Synthesis of Cyclohexylamine from Nitrobenzene, Chin. J. Chem. 2018, 36, 1191-1196.
2. Haiyan Wang, Jiayi Chen, Ruxue Fan, Yong Wang*, A Flexible Dual Solid-State Electrolyte Supercapacitor with Suppressed Self-Discharge and Enhanced Stability, Sustainable Energy & Fuels, 2018, 2, 2727-2732.
3. Lei Xie, Xuefeng Li, Jiang Deng, Yutong Gong, Haiyan Wang, Shanjun Mao, Yong Wang*, Sustainable and scalable synthesis of monodisperse carbon nanospheres and their derived superstructures, Green Chem. 2018, 20, 4596-4601.
4. Xiangqian Kong; Zhongfeng Fang; Xiaobing Bao; Zhe Wang; Shanjun Mao*; Yong Wang*， Efficient Hydrogenation of Stearic Acid over Carbon Coated Ni-Fe Catalyst, J. Catal. 2018, 367, 139-149.
5. Lei Xie, Haiyan Wang, Chunhong Chen, Shanjun Mao, Yiqing Chen, Haoran Li, Yong Wang*, Cooperative assembly of asymmetric carbonaceous bivalve-like superstructures from multiple building blocks, Research, 2018, 2018, 5807980.
6. Yueling, Cao; Bowen, Zhao; Xiaobing, Bao; Yong, Wang*. Fabricating metal@N-doped carbon catalysts via a thermal method. ACS Catal. 2018, 8, 7077-7085.
7. Chunhong Chen+, Xuefeng Li+, Jiang Deng, Zhe Wang, Yong Wang*, Shape Engineering of Biomass-Derived Nanoparticles from Hollow Spheres to Bowls via Solvent-Induced Buckling, ChemSusChem, 2018, 11, 2540-2546. (VIP Paper).
8. Haiyan, Jin; Jiayi, Chen; Shanjun, Mao; Yong, Wang*,Transition-metal induced the contraction of tungsten carbide lattice as superior hydrogen evolution reaction catalyst, 2018, ACS Appl. Mater. & Inter., 10, 22094–22101.
9. Haiyan Jin, Hao Zhang, Jiayi Chen, Shanjun Mao, Zheng Jiang* and Yong Wang*, A General Synthetic Approach for Hexagonal Phase Tungsten Nitride Composites and Their Application in Hydrogen Evolution Reaction, J. Mater. Chem. A. 2018, 6, 10967-10975.
10. Jiayi Chen, Haiyan Wang*, Jiang Deng, Chunmei Xu,Yong Wang*,Low-crystalline Tungsten Trioxide Anode with Superior Electrochemical Performance for Flexible Solid-state Asymmetry Supercapacitor. J. Mater. Chem. A. 2018, 6, 8986-8991.
11. Haiyan Wang, Ruxue Fan, Jingyu Miao, Jiayi Chen, Shanjun Mao, Jiang Deng and Yong Wang*, Oxygen vacancies on the surface of HxWO3-y for enhanced charge storage. J. Mater. Chem. A. 2018, 6, 6780-6784.
12. Xiangqian Kong, Yutong Gong,* Shanjun Mao, and Yong Wang*, Selective Hydrogenation of Phenol, ChemNanoMat, 2018, 4, 432-450.
13. Jing Wang, Zhongzhe Wei, ShanJun Mao, Haoran Li, Yong Wang*, Highly uniform Ru nanoparticles over N-doped carbon: pH and temperature-universal hydrogen release from water reduction, Energ. Environ. Sci., 2018, 11, 800-806.
14. Yiqing Chen, Xuefeng Li, Zhongzhe Wei, Shanjun Mao, Jiang Deng, Yueling Cao, Yong Wang*, Efficient synthesis of ultrafine Pd nanoparticles on an activated N-doping carbon for the decomposition of formic acid. Catal. Commun. 2018, 108, 55-58.
15. Zhongzhe Wei, Xuefeng Li, Jiang Deng, Jing Wang, Haoran Li, Yong Wang*,Improved catalytic activity and stability for hydrogenation of levulinic acid by Ru/N-doped hierarchically porous carbon. Molecular Catal. 2018, 448, 100-107.
16. Zhongzhe Wei, Yi Li, Jing Wang, Haoran Li, Yong Wang*, Chemoselective hydrogenation of phenol to cyclohexanol using heterogenized cobalt oxide catalysts, Chinese Chemical Letters, 2018, 29, 815-818.
17. Zhongzhe Wei, ShanJun Mao, Fanfei Sun, Jing Wang, Bingbao Mei, Yiqing Chen, Haoran Li and Yong Wang*,The synergic effects at molecular level in CoS2 for selective hydrogenation of nitroarenes, Green Chem. 2018, 20, 671-679.
18. 王哲, 毛善俊, 李浩然, 王勇*, 維生素E的催化合成路線分析(How to synthesize Vitamin E), 物理化學學報（Acta. Phys.-Chim. Sin), 2018, 34, 598-617.
19. Chunmei Xu, Haiyan Wang, Jiang Deng, Yong Wang*, High-performance Flexible Redox Supercapacitors Induced by Methylene Blue with a Wide Voltage Window.Sustainable Energy & Fuels, 2018, 2, 357-360.
20. Mingming Li, L. Yi, Lu Jia, Yong Wang*,Tuning the selectivity of phenol hydrogenation on Pd/C with acid and basic media, Catal. Commun. 2018, 103, 88-91.
2017年
1. Yueling Cao, Shanjun Mao, Mingming Li, Yiqing Chen, and Yong Wang*, Metal/porous carbon composites for heterogeneous catalysis: old catalysts with improved performance promoted by N-doping. ACS Catal. 2017,7,8090-8112.
2. Jiang Deng†, Michael R. Nellist‡, Michaela Burke Stevens‡, Christian Dette‡, Yong Wang†, and Shannon W. Boettcher*‡，Morphology Dynamics of Single-Layered Ni(OH)2/NiOOH Nanosheets and Subsequent Fe Incorporation Studied by in Situ Electrochemical Atomic Force Microscopy，Nano Lett., 2017,17,6922-6926.
3. Cao Yueling, Tang Minghui, Li Mingming, Deng Jiang, Xu, Fan, Xie Lei, Wang Yong*, In situ synthesis of chitin-derived Rh/N-C catalysts: efficient hydrogenation of benzoic acid and derivatives, ACS Sustainable Chem. Eng. 2017, 5, 9894-9902.
4. Mingming Li, Jiang Deng, Yikai Lan, Yong Wang*, Efficient Catalytic Hydrodeoxygenation of Aromatic Carbonyls over a Nitrogen-Doped Hierarchical Porous Carbon Supported Nickel Catalyst, ChemistrySelect. 2017, 2, 8486-8492.
5. Haiyan Wang, Chunmei Xu, Yiqing Chen and Yong Wang*，MnO2 nanograsses on porous carbon cloth for flexible solid-state asymmetric supercapacitors with high energy density, Energy Storage Mater. 2017, 8, 127-133.
6. Jing Wang, Zhongzhe Wei, Haiyan Wang, Yiqing Chen, Yong Wang*, CoOx-carbon nanotubes hybrids integrated on carbon cloth as a new generation of 3D porous hydrogen evolution promoter,J. Mater. Chem. A, 2017, 5, 10510-10516.
7. Xiaobing Bao, Jing Wang, Xu Lian, Haiyan Jin, Shiping Wang and Yong Wang*,Ni/Nitrogen-doped graphene nanotubes acted as a valuable tailor for remarkably enhanced hydrogen evolution performance of Platinum-based catalysts. J. Mater. Chem. A, 2017, 5, 16249-16254.
8. Minghui Tang‡, Shanjun Mao‡, Xuefeng Li, Chunhong Chen, Mingming Li and Yong Wang*, Highly effective Ir-based catalysts for the benzoic acid hydrogenation: experiment and theory guided catalysts rational design. Green Chem. 2017, 19, 1766-1774.
9. Haiyan Wang, Jiang Deng, Chunmei Xu, Yiqing Chen, Fan Xu and Yong Wang*, Ultramicroporous Carbon Cloth for Flexible Energy Storage with High Areal Capacitance, Energy storage Mater. 2017, 7, 216-221.
10. Jing Wang,Shanjun Mao, Zeyan Liu, Zhongzhe Wei, Haiyan Wang, Yong Wang*, The Dominating Role of Ni0 on the Interface of Ni/NiO for Enhanced Hydrogen Evolution Reaction. ACS Appl. Mater. Interfaces, 2017, 9, 7139-7147.
11. Chunhong Chen, Haiyan Wang, Chuanlong Han, Jiang Deng, Jing Wang, Mingming Li, Minghui Tang, Haiyan Jin, and Yong Wang*, Asymmetric flask-like hollow carbonaceous nanoparticles fabricated by the synergistic interaction between soft template and biomass. J. Am. Chem. Soc. 2017, 139, 2657-2663.
12. Lingfeng Shen, Shanjun Mao, Jianqing Li, Mingming Li, Ping Chen, Haoran Li, Zhirong Chen and Yong Wang*, PdZn intermetallic on a CN@ZnO hybrid as an efficient catalyst for the semi-hydrogenation of alkynols, J. Catal. 2017, 350, 13-20.
13. Jing Wang, Fan Xu, Haiyan Jin, Yiqing Chen and Yong Wang*, Non-noble Metal-based Carbon Composites in Hydrogen Evolution Reaction: Fundamentals to Applications, Adv. Mater. 2017, 29, 1605838.
14. Haiyan Jin, ShanJun Mao, Guopeng Zhan, Fan Xu, Xiaobing Bao and Yong Wang*. Fe incorporated α-Co(OH)2 nanosheet with remarkably improved activity and stability towards oxygen evolution reaction. J. Mater. Chem. A, 2017,5, 1078-1084.
15. Xiaobing Bao,‡ Yutong Gong,‡ Jiang Deng, Shiping Wang, Yong Wang* Organic acid-assisting Synthesis of 3D Lasagna-like Fe-N-doped CNTs-G Framework: An Efficient and Stable Electrocatalyst for Oxygen Reduction Reaction. Nano Research 2017, 10, 1258-1267.
2016年
1. Minghui Tang, Jiang Deng, Mingming Li, Xuefeng Li, Haoran Li ,Zhirong Chen and Yong Wang*. 3D-interconnected Hierarchical Porous N-doped Carbon Supported Ruthenium Nanoparticles as an efficient catalyst for Hydrogenation of Toluene and Quinoline. Green Chem.2016, 18, 6082-6090.
2. Zhongzhe Wei, Yiqing Chen, Jing Wang, Diefeng Su, Minghui Tang, Shanjun Mao, Yong Wang*. Cobalt encapsulated in N-doped graphene layers: an efficient and stable catalyst for hydrogenation of quinoline compounds. ACS. Catal., 2016，5816–5822
3. Fan Xu, Yiqing Chen, Minghui Tang, Haiyan Wang, Jiang Deng, and Yong Wang*, Acid Induced Self-Assembly Strategy to Synthesize Ordered Mesoporous Carbons from Biomass. ACS Sustainable Chem. Eng., 2016, 4，4473–4479.
4. Mingming Li, Minghui Tang, Jiang Deng, and Yong Wang*. Nitrogen-doped flower-like porous carbon directed by in situ hydrolysed MgO: Promising support for Ru nanoparticles in catalytic hydrogenations. Nano Res. 2016, 9，3129–3140.
5. Jiang Deng, Mingming Li, Yong Wang*, Biomass-derived Carbon: Synthesis and Application on Energy Storage and Conversion, Green Chem., 2016,18, 4824-4854
6. Jiang Deng, Tianyi Xiong, Haiyan Wang, Anmin Zheng, and Yong Wang*, Effects of Cellulose, Hemicellulose, and Lignin on the Structure and Morphology of Porous Carbons. ACS Sustainable Chem. Eng.,2016, 4, 3750–3756.
7. Wang, H. Y.; Deng, J.; Chen, Y .Q.; Xu, F.; Wei, Z. Z, and Wang, Y.* Hydrothermal synthesis of manganese oxide encapsulated multiporous carbon nanofibers for supercapacitors. Nano Research, 2016, 9, 2672-2680.
8. Li, M. M.; Xu, F.; Li, H. R. and Wang, Y.* Nitrogen-doped porous carbon materials: promising catalysts or catalyst supports for heterogeneous hydrogenation and oxidation. Catal. Sci. Technol. 2016, 6, 3670-3693.(2016 most accessed Catalysis Science and Technology articles)
9. Su, D. F.; Wei, Z. Z.; Mao, S. J.; Wang, J.; Li, Y.; Li, H. R.; Chen, Z. R.; Wang, Y.* Reactivity and mechanism investigation of selective hydrogenation of 2,3,5-trimethylbenzoquinone on in situ generated metallic cobalt. Catal. Sci. Technol., 2016, 6，4503–4510.
2015年
1. Wang, S. P.#; Wang, J.#; Zhu, M. L.; Bao, X. B.; Xiao, B. Y.; Su, D. F.; Li, H. R.; Wang, Y.* Molybdenum carbide-modified nitrogen-doped carbon vesicle encap-sulating nickel nanoparticles: A highly efficient, low-cost catalyst for hydrogen evolution reaction. J. Am. Chem. Soc. 2015, 137, 15753-15759.
2. Wei, Z. Z.#; Wang, J.#; Mao, S. J; Su, D. F; Jin, H. Y.; Wang, Y. H.; Xu, F.; Li, H. R.; Wang, Y.* In Situ Generated Co0-Co3O4/N-Doped Carbon Nanotubes Hybrids as Efficient and Chemoselective Catalysts for Hydrogenation of Nitroarenes. ACS. Catal. 2015, 5, 4783-4789.
3. Wang, J.; Wei, Z. Z.; Gong, Y. T.; Wang, S. P.; Su, D. F.; Han, C. L.; Li, H. R.; Wang, Y.* Ni-promoted Synthesis of Graphitic Carbon Nanotubes from in situ Produced Graphitic Carbon for Dehydrogenation of Ethylbenzene. Chem. Commun. 2015, 51, 12859-12862.
4. Deng, J.; Xiong, T. Y.; Xu, F.; Li, M. M.; Han, C. L.; Gong, Y. T.; Wang, H. Y.; Wang, Y.* Inspired by Bread Leavening: One-pot Synthesis of Hierarchically Porous Carbon for Supercapacitors. Green Chem. 2015, 7, 4053-4060.
5. Su, D. F.; Wang, J.; Jin, H. Y.; Gong, Y. T.; Li, M. M.; Pang, Z. F.; Wang Y.* From “Waste to Gold&rdqurdquo;: One-pot Way to Synthesize Ultrafinely Dispersed Fe2O3-based Nanoparticles on N-doped Carbon for Synergistically and Efficiently Water Splitting. J. Mater. Chem. A. 2015, 3, 11756-11761.
6. Wang, S. P.; Zhu, M. L.; Bao, X. B.; Wang, J.; Chen, C. H.; Li, H. R.; Wang, Y.* Efficient Synthesis of Mesoporous Fe-N/C Materials with High Catalytic Performance for Oxygen Reduction Reaction. ChemCatChem. 2015, 7, 2937-2944. (Invited)
7. Zhang, P. F.; Deng, J.; Mao, J. Y.; Li, H. R.; Wang, Y.* Selective aerobic oxidation of alcohols by a mesoporous graphitic carbon nitride/N-hydroxyphthalimide system under visible-light illumination at room temperature. Chin. J. Catal. 2015, 36, 1580-1586. (Invited)
8. Tang, M. H.; Mao, S. J.; Li, M. M.; Wei, Z. Z.; Xu, F.; Li, H. R.; Wang, Y.* RuPd Alloy Nanoparticles Supported on N-Doped Carbon as an Efficient and Stable Catalyst for Benzoic Acid Hydrogenation. ACS Catal. 2015, 5, 3100-3107.
9. Jin, H. Y.; Wang, J.; Su, D. F.; Wei, Z. Z.; Pang, Z. F.; Wang, Y.* In-situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bi-functional electrocatalysts for hydrogen and oxygen evolution. J. Am. Chem. Soc. 2015, 137, 2688-2694.
10. Gong, Y. T.; Li, M. M.; Wang, Y.* Carbon Nitride in Energy Conversion and Storage: Recent Advances and Future Prospects. ChemSusChem. 2015, 8, 931-946. (Invited Review).
11. Gong, Y. T.; Li, M. M.; Li, H. R.; Wang, Y.* Graphitic carbon nitride polymers: Promising catalysts or catalyst supports for heterogeneous oxidation and hydrogenation. Green Chem. 2015, 17, 715-736. (2015 most accessed Green Chemistry articles).
12. Wei, Z. Z.; Gong, Y. T.; Xiong, T. Y.; Zhang, P. F.; Li, H. R.; Wang, Y.* Highly efficient and chemoselective hydrogenation of α, βbeta;-unsaturated carbonyls over Pd/N-doped hierarchically porous carbon. Catal. Sci. Technol. 2015, 5, 397-404 .
2014年
1. Han, C. L.; Wang, S. P.; Wang, J.; Li, M. M.; Deng, J.; Li, H. R.; Wang, Y.* Controlled Synthesis of Sustainable N-doped Hollow Core Mesoporous Shell Carbonaceous Nanospheres from Biomass. Nano. Res. 2014,7, 1809-1819.
2. Wang, S. P.; Han, C. L.; Wang, J.; Deng, J.; Zhu, M. L.; Yao, J.; Li, H. R.; Wang, Y.* Controlled Synthesis of Ordered Mesoporous Carbohydrate-derived Carbons with Flower-like Structure and N-doping by Self-transformatio. Chem. Mater. 2014, 26, 6872-6877.
3. Gong, Y. T.; Wang, H. Y.; Wei, Z. Z.; Xie, L.; Wang, Y.* An efficient way to introduce hierarchical structure into biomass-based hydrothermal carbonaceous materials. ACS Sustain. Chem. Eng. 2014, 2, 2435-2441.
4. Wang, S. P; Liu, R. H.; Han, C. L; Wang, J.; Li, M. M.; Yao, J.*; Li, H. R.; Wang, Y.* A novel strategy to synthesize hierarchical porous carbohydrate-derived carbon with tunable properties. Nanoscale, 2014, 6, 13510-13517.
5. Wang, H. Y; Gong, Y. T.; Wang, Y.* Cellulose-based hydrophobic carbon aerogels as versatile, and superior adsobents for sewage treatment. RSC Adv. 2014, 4, 45753-45759.
6. Gong, Y. T.; Xie, L.; Li, H. R.; Wang, Y.* Sustainable and scalable production of monodisperse and highly uniform colloidal carbonaceous spheres using sodium polyacrylate as dispersant. Chem. Commun. 2014, 50, 12633-12636.
7. Jin, H. Y.; Xiong, T. Y.; Li, Y.; Xu, X.; Li, M. M.; Wang, Y.* Improvedelectrocatalytic activity for ethanol oxidation by Pd@N-doped carbon from biomass. Chem. Commun. 2014, 50, 12637-12640.
8. Gong, Y. T.; Wei, Z. Z.; Wang, J.; Zhang, P. F.; Li, H. R.; Wang, Y.* Design and Fabrication of Hierachically Porous Carbon with a Template-free Method. Sci. Rep. 2014, 4, 6349.
9. Xu, X.; Li, H. R.; Wang, Y.*Selective Hydrogenation of Phenol to Cyclohexanone in Water over Pd@N-doped Carbon Derived from Ionic Liquids Precursors. ChemCatChem. 2014, 6, 3328-3332.
10. Xu, X.; Tang, M. H.; Li, M. M.; Li, H. R.; Wang, Y.* Hydrogenation of Benzoic Acid and Derivatives over Pd Nanoparticles Supported on N-doped Carbon Derived from Glucosamine Hydrochloride. ACS Catal. 2014, 4, 3132-3135.
11. Zhang, P. F.; Gong, Y. T.; Wei, Z. Z.; Wang, J.; Zhang, Z. Y.; Li, H. R.; Dai, S.; and Wang, Y.* Updating Biomass into Functional Carbon Material in Ionothermal Manner. ACS Appl. Mater. Interfaces. 2014, 6, 12515-12522
12. Li, M. M.; Xu, X.; Gong, Y. T.; Wei, Z. Z.; Hou, Z. Y.; Li, H. R.; Wang, Y.* Ultrafinely Dispersed Pd Nanoparticles on a CN@MgO Hybrid as a Bifunctional Catalyst for Bioderived Compounds Upgrading. Green Chem. 2014, 16, 4371-4377.
13. Zhang, P. F.; Li, H. R.; Wang, Y.* Post-Functionalization of Graphitic Carbon Nitride by Grafting Organic Molecule: Toward C-H Bond Oxidation Using Atmospheric Oxygen. Chem. Commun. 2014, 50, 6312-6315.
14. Gong, Y. T.; Wang, J.; Wei, Z. Z.; Zhang, P. F.; Li, H. R.; Wang, Y.* Combination of carbon nitride and carbon nanotubes: catalysts in energy conversion. ChemSusChem. 2014, 7, 2303-2309.
15. Wang, J.; Xu, Z.; Gong, Y. T.; Han, C. L.; Li, H. R.; Wang, Y.* One-Step Production of Sulfur and Nitrogen Co-doped Graphitic Carbon for Oxygen Reduction: Activation Effect of Oxidized Sulfur and Nitrogen. ChemCatChem. 2014, 6, 1204-1209.
16. Chen, K. X.; Zhang, P. F.; Wang, Y.; Li, H. R.* Metal-free allylic/benzylic oxidation strategies with molecular oxygen: recent advances and future prospect. Green Chem. 2014, 16, 2344-2374. Invited Review
17. Song, T.; Zhou, B.; Peng, G. W.; Zhang, Q. B.; Wu, L. Z.; Liu, Q.*, Wang, Y.*. Aerobic Oxidative Coupling of Resveratrol and its Analogues by Visible Light Using Mesoporous Graphitic Carbon Nitride (mpg-C3N4) as a Bioinspired Catalyst. Chem. A Eur. J. 2014, 20, 678-682.
18. Han, C. L.; Wang, J.; Gong, Y. T.; Xu, X.; Li, H. R.; Wang, Y.* Nitrogen-Doped Hollow Carbon Hemispheres as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction in Alkaline Medium. J. Mater. Chem. A, 2014, 2, 605-609.
2013年
1. Soll, S.; Zhang, P. F.; Zhao, Q.; Wang, Y.; Yuan, J. Y.* Mesoporous Zwitterionic Poly(ionic liquid): Intrinsic Complexation and Efficient Catalytic Fixation of CO2. Polymer, 2013, 4, 5048-5051.
2. Deng, D. X.;* Yang, Y.; Gong, Y. T.; Li, Y.; Xu, X.; Wang, Y.* Palladium nanoparticles supported on mpg-C3N4 as active catalyst for semihydrogenation of phenylacetylene under mild conditions.Green Chem.2013, 15, 2525-2531.
3. Yao, Y.; Xue, M.; Zhang, Z. B.; Zhang, M. M.; Wang, Y.; Huang, F. H.* Gold nanoparticles stabilized by an amphiphilic pillar
4. Li, Y.; Xu, X.; Zhang, P. F.; Gong, Y. T.; Li, H. R.; Wang, Y.*Highly Selective Pd@mpg-C3N4 Catalyst for Phenol Hydrogenation in Aqueous Phase. RSC Adv. 2013, 3, 10973-10982.
5. Zhang, P. F.; Yuan, J. Y.*; Tim-Patrick,F.; Antonietti, M.; Li, H. R.; Wang, Y.* Improving Hydrothermal Carbonization by Poly(ionic liquid)s. Angew. Chem. Int. Ed. 2013, 52, 6028-6032.
6. Zhang, P. F.; Gong, Y. T.; Li, H. R.; Chen, Z. R.; Wang, Y.* Selective oxidation of benzene to phenol by FeCl3/mpg-C3N4 hybrids. RSC Adv. 2013, 3, 5121-5126.
7. Zhang, P. F.; Gong, Y. T.; Li, H. R.; Chen, Z. R.; Wang, Y.* Solvent-free aerobic oxidation of hydrocarbons and alcohols with Pd@N-doped carbon from glucose. Nat. Commun. 2013, 4, 1593.
8. Zhang, P. F.; Yuan, J. Y.; Li, H. R.; Liu, X. F.; Xu, X.; Antonietti, M.; Wang, Y.* Mesoporous Nitrogen-Doped Carbon for Copper-Mediated Ullmann-type C-O/-N/-S Cross-Coupling Reactions. RSC. Adv., 2013, 3, 1890-1895.
9. Gong, Y. T.; Zhang, P. F.; Xu, X.; Li, Y.; Li, H. R.;Wang, Y.* A Novel Catalyst Pd@ompg-C3N4 for Highly Chemoselective Hydrogenation of Quinoline under Mild Conditions, J. Catal. 2013, 297, 272-280.
2012年
1. Xu, X.; Li, Y.; Gong, Y. T.; Zhang, P. F.; Li, H. R.; Wang, Y.* Synthesis of Palladium Nanoparticles Supported on Mesoporous N-Doped Carbon and Their Catalytic Ability for Biofuel Upgrade. J. Am. Chem. Soc. 2012, 134, 16987-16990.
2. Li, Y.; Gong, Y. T.; Xu, X.; Zhang, P. F.; Li, H. R.; Wang, Y.* A practical and benign synthesis of amines through Pd@mpg-C3N4 catalyzed reduction of nitriles. Catal. Commun. 2012, 28, 9-12.
3. Zhang, P. F.; Wang, Y.*; Li, H. R.*; Antonietti, M. Metal-free oxidation of sulfides by carbon nitride with visible light illumination under room temperature. Green Chem. 2012, 7, 1904-1908.
4. Zhang, P. F.; Gong, Y. T.; Lv, Y. Q.; Guo, Y.; Wang, Y.; Wang, C. M.; Li, H. R.* Ionic liquids with metal chelate anions. Chem. Commun. 2012, 48, 2334-2336.
5. Wang, Y.; Wang, X.; Antonietti, M.* Polymeric graphitic carbon nitride as a heterogenous organocatalyst: from photochemistry to multipurpose catalysis in sustainable chemistry. Angew. Chem. Int. Ed. 2012, 51, 68-89. invited review.
2011年
1. Zhu, X.; Wang, Y.; Li, H.* Do all the protic ionic liquids exist as molecular aggregates in the gas phase? Phys. Chem. Chem. Phys., 2011, 13, 17445-17448.
2. Zhang, P.; Wang, Y.; Yao, J.; Wang, C.; Antonietti, M.; Li, H.* Visible-light-induced metal-free allylic oxidation utilizing a coupled photocatalytic system of g-C3N4 and N-hydroxy compounds. Adv. Synth. & Catal. 2011, 353, 1447-1451.
3. Wang, Y.;* Yao, J.; Li, H.;* Su, D.; and Antonietti, M. Highly selective hydrogenation of phenol and derivatives over a Pd@carbon nitride catalyst in aqueous media. J. Am. Chem. Soc. 2011,133, 2362-2365.
4. Wang, Y.;* Li, H.; Yao, J.; Wang, X.; and Antonietti, M. Synthesis of boron doped polymeric carbon nitride and their use as metal-free catalysts for aliphatic C-H bond oxidation. Chem. Sci. 2011, 2, 446-450. (Highlighted by Chem. & Eng. News, 2010-12-13, amongst the top ten accessed articles).
2010年
1. Wang, Y.;* Zhang, J.; Wang, X.; Antonietti, M.; and Li, H.* Boron- and fluorine-containing mesoporous carbon nitride polymers: metal-free catalysts for cyclohexane oxidation. Angew. Chem. Int. Ed. 2010, 49, 3356-3359.
2. Wang, Y.; Wang, X.; Antonietti, M.; and Zhang, Y.* Facile one-pot synthesis of nanoporous carbon nitride solids by using soft templates. ChemSusChem, 2010, 3, 435-439.
3. Wang, Y.;* Di, Y.; Antonietti, M.; Li, H.; Chen, X.; and Wang, X. Excellent visible-light photocatalysis of fluorinated polymeric carbon nitride solids. Chem. Mater. 2010, 22, 5119-5121.
4. Gao, Y.; Zhang, L. Q.; Wang, Y.; and Li, H.* Probing electron density of H-bonding between cation-anion of imidazolium-based ionic liquids with different anions by vibrational spectroscopy. J. Phys. Chem. B 2010, 113, 2828-2833.
2009年
1. Wang, Y.; Xu, Z.; Gao, Y.; and Li, H.* Probing the strength changes in C-H and C-C bonds for cation/pi complexes. J. Phys. Chem. A 2009, 113, 7097-7102.
2. Zhu, X.; Wang, Y.; and Li, H.* The structural organization in aqueous solutions of ionic iquids. AIChE J. 2009, 55, 198-205.
3. Zhang, L.; Wang, Y.; Xu, Z.; and Li, H.* Comparison of the blue-shifted C-D stretching vibrations for D">J. Phys. Chem. B 2009, 113, 5978-5984.
4. Wang, C.; Guan, W.; Xie, P.; Yun, X.; Li, H.;* Hu, X.; Wang, Y. Effects of ionic liquids on the oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone under atmospheric oxygen. Catal. Commun. 2009, 5, 725-727.
2008年
1. Wang, Y.; Wang, C.; Zhang, L.; and Li, H.* Difference for SO2 and CO2 in TGML ionic liquids: a theoretical investigation. Phys. Chem. Chem. Phys. 2008, 10, 5976-5982.
2. Zhang, L.; Xu, Z.; Wang, Y.; and Li, H.* Prediction of the solvation and structural properties of ionic liquids in water by two-dimensional correlation spectroscopy. J. Phys. Chem. B 2008, 112, 6411-6419.
3. Guan, W.; Wang, C.; Yun, X.; Hu, X.; Wang, Y.; and Li, H.* A mild and efficient oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone in ionic liquids. Catal. Commun. 2008, 9, 1979-1981.
2007年
1. Wang, Y.; Pan, H.; Li, H.;* and Wang, C. The force field of the TMGL ionic liquid and the solubility of SO2 and CO2 in the TMGL from molecular dynamics simulation. J. Phys. Chem. B 2007, 111, 10461-10467.
2. Zhang, L.; Li, H.;* Wang, Y.; and Hu, X. Characterizing the structural properties of N,N-dimethyl formamide-based ionic liquid: a density-functional study. J. Phys. Chem. B 2007, 111, 11016-11020.
3. Xu, X.; Wang, C.; Li, H.;* Wang, Y.; Sun, W.; and Shen, Z. Effects of imidazolium salts as cocatalysts on the copolymerization of CO2 with epoxides catalyzed by (Salen) Cr(ш)Cl complex. Polymer, 2007, 48, 3921-3924.
2006年
1. Wang, Y.; Li, H.;* and Han, S. A theoretical investigation of the interactions between water molecules and ionic liquids. J. Phys. Chem. B 2006, 110, 24646-24651.
2. Wang, Y.; Li, H.;* and Han, S. The chemical nature of the +C-H…X- (X= Cl or Br) interaction in imidazolium halide ionic liquids. J. Chem. Phys. 2006, 124, 044504.
3. Wang, C.; Guo, L.; Li, H.;* Wang, Y.; Weng, J.; and Wu, L. Preparation of simple ammounium ionic liquids and their application in the cracking of dialkoxypropanes. Green Chem. 2006, 8, 603-607.
4. Jiang, H.; Wang, C.; Li, H.;* and Wang, Y. Preparation of dialkoxypropanes in simple ammonium ionic liquids. Green Chem. 2006, 8, 1076-1079.
5. Weng, J.; Wang, C.; Li, H.;* and Wang, Y. Novel quaternary ammonium ionic liquids and their use as dual solvent-catalysts in the hydrolytic reaction. Green Chem. 2006, 8, 96-99.
6. 韓衛華，李浩然，* 鄧東順，王勇，硼氫化鈉還原潛手性酮反應機理研究. 化學學報，2006, 64, 1723-1729.
2005年
1. Wang, Y.; Li, H.; Wu, T.; Wang, C.; and Han, S. Reaction mechanism study for the synthesis of alkylimidazolium-based halide ionic liquids. Acta Phys. –Chim. Sin. 2005, 21, 517-522.
2. Wang, Y.; Li, H.;* and Han, S. Structure and conformation properties of 1-alkyl- 3-methylimidazolium halide ionic liquids: A density functional theory study. J. Chem. Phys. 2005, 123, 174501.
2004年
1. 王勇，李浩然，*王從敏，許映杰，韓世鈞，物理化學學報，單重態二溴卡賓與甲醛環加成反應的量化研究. 2004，20，1339-1344.
2. Xu, Y.; Li, H.;* Wang, C.; Wang, Y.; and Han, S. Bubble points measurement for (triethyl orthoformate + diethyl malonate). J. Chem. Thermodyn. 2004, 36, 971-976.
3. Wang, Y.; Li, H.;* Wang, C.; and Jiang, H. Ionic liquids as catalytic green solvents for cracking reactions. Chem. Commun. 2004, 1938-1839.
榮譽獎勵：
1.王勇，王靜，王世萍，金海燕，毛善俊，浙江省自然科學一等獎（2023）
2.王勇，毛善俊，王哲，浙江省專利一等獎（2023）
3.王勇，呂國鋒，于麗麗，王哲，毛善俊，唐靜思，李浩然，陳志榮，中國專利金獎（2023）
4.王勇，中國化學會催化委員會第九屆中國催化青年獎（2023）
5.王勇，中國化工學會侯德榜化工科技-創新獎（2022）
6.2021年度新昌縣十佳創新團隊-浙江大學王勇團隊
7.王勇，馬嘯，于麗麗，王哲，毛善俊，李建清，陳鋼，李浩然，陳志榮，2021，中國石油與化學工業聯合會專利金獎
8.王勇，毛善俊，于麗麗，呂國鋒，王哲，2020年度浙江省科技獎-技術發明一等獎
9.王勇，陳志榮，呂國鋒，毛善俊，王哲，李浩然，于麗麗，馬嘯，黃國東，胡柏剡等，2020，中國石油與化學工業聯合會技術發明特等獎
10.2019年度新昌縣科技創新優秀專家團隊-浙江大學王勇團隊
11.王勇，青年科技突出貢獻獎，2018，中國石油和化學工業聯合會
12.李浩然，馬嘯，胡柏剡，趙文樂，毛建擁，王勇，邱金倬，方萬軍，陳為超，仇丹，2018，中國輕工業聯合會科學技術進步一等獎
13.王勇，國家高層次人才特殊支持計劃青年拔尖人才，2015，中共中央組織部，人力資源和社會保障部
14.王勇，中國催化新秀獎，2014，中國化學會催化專業委員會
15.王勇，浙江省優秀博士后，2011，浙江省人力資源和社會保障廳
16.王勇，全國優秀博士學位論文提名論文，2010，教育部
王勇，浙江大學化學系特聘研究員，浙江大學–馬普膠體與界面化學研究所“國際伙伴小組”組長。1979年出生于湖南汨羅，2002年本科畢業于湘潭大學，2007年博士畢業于浙江大學化工系，博士論文被評為浙江省優秀博士論文以及全國百篇優秀博士論文提名獎論文。2007年～2009年在浙江大學化學系從事博士后研究工作，合作導師李浩然教授，并榮獲“浙江省優秀博士后”稱號。2009年～2011年在德國馬普膠體與界面化學研究所從事博士后研究工作，合作導師Markus Antonietti教授。2014年榮獲“中國催化新秀獎”。2011年進入浙江大學工作至今，作為項目負責人承擔多項國家自然科學基金、浙江省杰出青年基金及教育部博士點基金等。擔任國際期刊Scientific Reports的編委。王勇研究組致力于新材料，尤其是新型多功能炭材料的開發以及多功能材料在傳統多相催化反應，能源高效存儲和轉化等方面的應用。迄今已在Nat. Commun.,J. Am. Chem. Soc.; Angew. Chem. Int. Ed.; Chem. Mater.; J. Catal.等國際知名刊物上發表科研論文70余篇，H因子25。
一、功能炭材料的設計合成
炭材料因其優異的水熱穩定性、良好的導電性、可修飾性和易于后處理等特性在作為催化劑載體和能源存儲和轉化材料(如超級電容器和燃料電池等)方面備受關注和研究。而傳統的碳基材料如活性炭等在諸多方面無法適應實際應用中的要求（比表面積，孔道結構，表面化學性質等）。為了達到提高炭材料在催化或能源方面的利用效率，降低炭材料的生產成本等目的，需要設計合成具有特定功能或多功能的碳基材料。
1. 生物質基功能炭材料的開發
化石燃料的急劇消耗讓以石油產品為碳源的炭材料合成方法前景堪憂。反之，以可再生的生物質為原料的炭材料合成方法表現出巨大的應用潛力。生物質水熱法制備炭材料雖然具有原料來源廣、生產成本低、可持續性好等特點，但孔道結構缺乏，水熱產品形貌難控制等缺點一直限制其更廣泛的應用。王勇研究組以水熱法為基礎，開發了微量添加劑輔助法可控合成了低尺寸炭微球以及尺寸均一的單分散炭微球，克服了生物質水熱碳化法的產品形貌不均一，尺寸分布不一，尺寸難控制的缺點。另外研究組以水熱法結合模板法技術，合成了中空、多孔生物質基功能炭材料，解決了軟模板法難以合成有序多孔炭材料的難題。雜原子摻雜是調控碳基材料物理化學性質的有效方法。王勇團隊利用水熱合成法，原位焙燒法等合成了氮摻雜的多孔炭材料，通過在炭材料中引入電負性強的氮元素調變碳的電子結構，從而達到增強炭材料催化活性的目的。這些成果為炭材料的可控合成和應用提供了新方向。
2. 碳基復合材料的設計合成
單一炭材料活性低，無法滿足實際應用中對材料活性及多功能化的需求。開發碳基復合材料是提高碳基材料活性的有效途徑，但是如何將多孔炭材料與納米金屬或金屬氧化物等進行有效地復合，提高碳基納米復合材料的催化活性，是一大挑戰。王勇研究團隊針對催化和能源轉化應用中的需求，開發了多種炭-炭復合材料，金屬-炭和氧化物-炭復合材料。從納米尺度，甚至是原子、分子尺度對碳基多相催化劑（電催化劑）的結構進行了有效的調控，極大地提高了其催化活性，拓展了其應用范圍。如以生物質為碳源，通過與廉價金屬Co復合制備得到CoOx@CN材料，該材料不僅是催化苯酚、硝基化合物等選擇性加氫的優異催化劑，還能夠高效地電催化水分解制備H2和O2。
二、碳基納米催化劑在傳統多相催化反應中的應用
1.在高效選擇性加氫反應中的應用
優異的水熱穩定性和高比表面積使得碳基材料成為非均相催化劑載體的理想選擇。王勇研究員于2011年發現石墨型氮化碳作為載體負載納米Pd(Pd@C3N4)催化苯酚加氫，在低溫低壓下即可獲得高苯酚轉化率(>99%)和高環己酮選擇性(>99%)，解決了苯酚選擇性氫化高轉化率和高選擇性無法兼容的難點。實驗研究和DFT計算研究表明，催化劑的高活性和高穩定性源于氮化碳中氮元素有利于提高Pd納米顆粒的分散性并有效抑制Pd納米顆粒的流失。催化劑的高選擇性來源于氮化碳材料對底物苯酚的選擇性吸附。不僅對于C=O的選擇性加氫，Pd@C3N4對于C=N,C≡N和C≡C都具有優異的催化性能，如Pd@C3N4能催化喹啉高選擇性氫化至1,2,3,4-四氫喹啉，苯乙炔到苯乙烯，腈基到叔胺等。
不僅具有高氮含量(氮含量=60 %)的氮化碳材料，以離子液體或氨基葡萄糖鹽酸鹽為原料制備的氮摻雜（氮含量≈10 %）多孔碳基材料作為Pd納米催化劑的載體同樣具有優異的催化性能。Pd@CN能高效地催化苯酚選擇性加氫制備環己酮以及木質素模型分子-香蘭素的加氫脫氧，同時還是催化苯甲酸選擇性加氫的優異催化劑，且發現雙金屬Ru-Pd具有更加優異的催化活性。研究發現氮的含量及種類對催化活性有明顯影響，這些研究結果為高效、高選擇性加氫催化劑的設計提供了方向和理論依據。
2.在選擇性氧化反應中的應用
針對環己烷選擇性氧化制備環己酮等關鍵碳氫鍵氧化反應，王勇課題組開發了氮化碳與有機小分子NHPI的組合型催化劑，通過氮化碳與NHPI之間的電子轉移極大地提高了催化劑的氧化活性。這種組合催化劑的思想還被成功地應用于醇類、硫化物等底物的選擇性氧化反應中。以氮摻雜的多孔炭材料負載Pd納米顆粒，以氧氣或空氣作為氧化劑，實現了C-OH和C-H鍵的高效、高選擇性氧化反應。其中催化苯乙醇氧化至苯乙酮的TOF值可達到212,576 h-1，遠高于其他載體負載的同類Pd催化劑。Pd-N之間的相互作用、小的Pd納米尺寸和底物的有效吸附決定了該催化過程的高活性和高選擇性。該類催化劑的開發有望解決傳統催化中強氧化劑的使用和選擇性差的問題。
三、碳基納米催化劑在能源轉化和存儲方面的應用
1.能源儲存 碳基納米材料，尤其是多孔炭材料以其高比表面積、優異導電性成為雙電層電容器的理想材料。炭材料的孔道結構是決定電容器性質的關鍵因素之一。王勇研究組以生物質為碳源，設計合成了多種多級大孔-介孔-微孔炭材料，材料不僅具有高達1000-2000 m2/g的比表面積，同時具有大孔-介孔比例高的特點，保證了材料不僅電解質吸附位點多且適于離子的傳輸，因而表現出優異的電荷儲存和傳輸性能。
2.能源轉化
作為可再生資源，醇類燃料(甲醇，乙醇)或氫能等成為替代化石能源最具前景的選擇。燃料電池是高效轉化醇類化學能到電能的裝置，如何減少甚至消除昂貴的Pt基催化劑的使用是實現燃料電池大規模使用的關鍵。氮摻雜的碳基材料在燃料電池的陰極氧還原反應中表現出優于Pt基材料的高穩定性和低成本的優點。研究組開發的g-C3N4/CNTs復合材料和中空氮雜碳基微球在燃料電池陰極氧還原中性能優異。為進一步提高碳基材料的ORR活性，課題組在碳基材料中引入廉價金屬如Fe等，制備得到Fe-N-C復合材料。該材料在堿性介質中表現出比Pt/C更優異的電催化活性與穩定性，在酸性條件下，Fe-N-C復合材料也具有優異的ORR活性。
在電解水制氫中，昂貴Pt/C催化劑的使用同樣限制了其廣泛應用，研究組開發的CoOx@CN材料催化劑具有接近Pt基催化劑的催化活性，該催化劑亦可作為析氧反應的催化劑，為非貴金屬催化劑催化電解水提供了可能。
來源：科學成果管理與研究 2015年第8期
中國科技創新人物云平臺暨“互聯網+”科技創新人物開放共享平臺（簡稱：中國科技創新人物云平臺）免責聲明：
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